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Game: Spawn: The Demon's Hand
Platform:
Cheats & Hints:

Boss Characters:
There are four more characters to be unlocked, but they can only be unlocked in the multiplayer mode. In order to unlock these, you must defeat the Boss mode without continuing! The number of times you do this determines which character will be unlocked. Which characters you play to do this doesn't matter. However, I suggest using two of the strongest characters. The Gatekeeper & Gatekeeper team worked great for me!

One time - Spawn I
Five times - Dark Ages Spawn
Ten times - Spawn IV
Fourteen times - Admonisher

Note:
You'll notice that if you get passed the Gatekeeper level without continuing, a new Boss level appears. Instead of fighting Malebolgia at level 12, you'll fight Angel Teneres. Then, level 13 is Dark Ages Spawn. Finally, level 14 has you fighting Malebolgia.

Black Brimstone:
To play as Black Brimstone beat the game with all characters then Highlight Brimstone and hold the two back triggers and press A. Viola! Black Brimstone